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Line bottom of 4 (125 ml capacity) ramekins* or custard cups with a round of waxed paper, then grease; set aside.
Microwave chocolate in medium microwave-safe bowl on High for 45 seconds or until chocolate is melted, stirring every 10 seconds to stop from burning
Stir in Hellmann's Original Mayonnaise until smooth.
Beat in granulated sugar and flour with wire whisk until blended.
Beat in eggs and vanilla.
Evenly spoon into prepared ramekins. Refrigerate 1 hour or until ready to bake.
Preheat oven to 180°C. Arrange ramekins on baking sheet. Bake for 13 minutes or until edges are firm but centres are still slightly soft. (Do Not Over Bake.)
On wire rack, cool 5 minutes.
To serve, carefully run sharp knife around cake edges. Unmold onto serving plates, then remove waxed paper. Sprinkle with icing sugar and serve immediately.
*To bake in 12-cup muffin pan, line bottoms of 8 muffin cups with waxed paper, then grease.
Evenly spoon in batter. Refrigerate as above. Bake at 180°C for 9 minutes or until edges are firm but centres are still slightly soft. (Do Not Over Bake.)
On wire rack, cool for 5 minutes. To serve, carefully run sharp knife around cake edges and gently lift out of pan. (Do not turn pan upside-down to unmold.)
Arrange cakes, bottom side up, on serving plates, 2 cakes per serving. Remove waxed paper and sprinkle as above.